Yes. there is a sequence process that works for some and not for others.
I strongly suggest you buy another blank, at least one; and have it programmed by an auto electrician.
It won't be cheap, but neither is being locked out of your vehicle if you lose your only key.
4D67 is the chip type, but they are not battery operated.
Hopefully the problem is the key, and not the ignition part of the immobiliser.
Another potential problem is that, when I had my sets of keys made, a master key was required, which, thankfully, I had.
The auto-locksmith that did mine made additional master keys; more expense but more peace of mind.
Good luck.